You would want to check with your local store first but most Best Buys will charge a fee for your to leave your old TV there.
Best Buy accepts most electronics and large appliances, with a few exceptions. ... All U.S. stores, including those in Puerto Rico, offer the in-store programs for customers to bring their old, unused, or unwanted consumer electronics for recycling, no matter where they were purchased.
https://www.bestbuy.com/site/recycling/recycle-faqs/pcmcat174700050009.c?id=pcmcat174700050009
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